Semiconductor technology & processing

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EUV lithografie: opties voor reken- en geheugenchips in de weegschaal

Imec neemt een grote sprong voorwaarts in het begrijpen en verleggen van de grenzen van extreme ultraviolette lithografie — deel 1

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Dit artikel is enkel beschikbaar in het Engels.

In 2019, EUV lithography (EUVL) will reach an important milestone. After many years of waiting for implementation, the advanced lithography technique is finally moving into high-volume manufacturing. First insertion of EUVL is planned for printing the most critical metal layers (and vias) of the N7 (i.e., imec N8 or foundry N7) logic back-end-of-line (BEOL). At the same time, research centers are exploring the options for future technology nodes, which will gradually incorporate more EUVL printed structures. In a first part of this article, Stefan Decoster, R&D dry etch engineer at imec, compares different (multi-)patterning approaches for the N3 and beyond technology nodes, and highlights their pros and cons.

More than in the past, researchers are now also considering EUVL as an option for patterning critical memory structures, such as the pillars for dense dynamic random access memory (DRAM) applications. Another example is the introduction of EUVL in the fabrication process of the spin-transfer-torque magnetic random access memory (STT-MRAM). In a second part of the article, Murat Pak, R&D engineer at imec presents several approaches for patterning the STT-MRAM key building block. 

Introducing EUVL multi-patterning in the back-end-of-line

This year, some of the major foundries will for the first time use EUVL in their high-volume manufacturing line for processing N7 (i.e., imec N8 or foundry N7) chips for logic applications. They will insert EUVL into the most critical metal layers of the BEOL (referred to as the local M0 to M3 layers), and in the vias that interconnect these metal layers. In these layers, lines and trenches have pitches of the order of 36-40nm. The trenches are complemented with block layers perpendicular to the trenches, in order to create disconnections in the continuous trenches. The next technology node N5 (or imec N7) focuses on pitches between 32 and 28nm. 

“In 2017, we already demonstrated that these 32nm pitch lines can be patterned directly with EUVL in one single exposure,” adds Stefan Decoster. “Alternatively, a hybrid option can be used in which 193nm immersion lithography based self-aligned quadrupole patterning (SAQP) is combined with a direct EUV print of the block layer.” SAQP is a multi-patterning variant that relies on one lithography step (to create a pre-pattern of lines) and additional deposition and etch steps (to create spacer-like features). As a result, each initial line of the pre-pattern ends up in four lines with a four times denser pitch.

Illustration of a 32nm pitch M2 layer patterned with 193nm immersion-based SAQP in combination with a direct EUV print of the block layer.

Illustration of a 32nm pitch M2 layer patterned with 193nm immersion-based SAQP in combination with a direct EUV print of the block layer.

From EUVL single-patterning to EUVL multi-patterning

Meanwhile, it has become clear that EUVL single-patterning – and hence the advantages that it brings along – reaches its limits at 32nm to 30nm pitches. Stefan Decoster: “Beyond 30nm pitches, the use of current EUVL technologies (i.e., with 0.33 numerical aperture (NA)) will need to be complemented with multi-patterning techniques, which allow a further shrink of dimensions. These techniques in general involve splitting a chip pattern into two or more simpler masks and can exist in different flavors. Multi-patterning EUVL will be introduced somewhat sooner than originally thought – mainly due to the presence of stochastic failures.” These failures start to become more relevant at extremely small feature sizes and limit the practical resolution of single-exposure EUVL. 

Multi-patterning options for the imec N5 technology node

In practice, this means that the most critical metal layers of the imec N5 (or foundry N3) technology nodes (with pitches as tight as 21nm) require EUVL multi-patterning techniques, such as self-aligned double patterning (SADP) or litho-etch litho-etch (involving two EUVL steps). Alternatively, imec showed that lines and trenches at these dimensions can still be achieved with 193nm immersion-based SAQP, or, alternatively, with immersion-based self-aligned octupole patterning (SAOP). Each of these techniques comes with its own set of advantages and disadvantages, in terms of cost-of-ownership, litho performance or complexity of the process flow. 

“However, this is certainly not the end of EUVL single patterning,” clarifies Stefan Decoster. “We expect that the more relaxed metal layers (such as M4 to M7 layers) and the critical vias can still take advantage of EUVL single exposure for the following technology nodes (beyond imec N7 (foundry N5)). Also, imec and ASML are working on the next-generation of high-NA EUVL systems (with NA = 0.55), to further push the resolution for single exposures.”

Beyond imec N5: patterning options for 16nm pitch lines, trenches and blocks 

Imec researchers have explored four different multi-patterning options for printing lines and blocks at pitches below 20nm: 193nm immersion based SAOP, EUV-based SADP,  EUV-based SAQP, and self-aligned litho-etch litho-etch (SALELE). Stefan Decoster: “All four candidates have the potential of printing 16nm pitch lines. They differ however in terms of process complexity, cost-of-ownership, scalability and freedom in design - which are important considerations for the industry. We also found that line-edge roughness remains a major concern for the majority of the options.”

193nm immersion lithography can still do the job...

At these aggressive pitches, 193nm immersion lithography can only be used in combination with SAOP – which involves three times a patterning doubling approach, starting from 128nm pitches. Stefan Decoster: “The good thing about immersion-based SAOP is the small line-edge roughness. But an intrinsic drawback is the extremely long and complex process flow, which creates challenges for process control and cost.” 

... but shorter flows can be obtained with EUVL multi-patterning

“For this reason, we also explored ‘shorter’ EUVL-based multi-patterning flows, starting with EUV-based SADP”, adds Stefan Decoster. “To enable this double-patterning approach, the starting pitch at EUV lithography must be 32nm. Although current EUVL technology is still capable of printing 32nm pitch lines (which refers to the distance between the lines), the resulting line width can however not be printed smaller than 16nm. Therefore, we had to apply additional trimming techniques to realize the target 8nm lines at 32nm pitch. With the SADP technique, this pitch could successfully be reduced to 16nm.” 16nm pitch lines and trenches were also successfully printed with the more scalable EUVL SAQP approach – starting with an initial, more relaxed 64nm pitch. For these EUV-based multi-patterning approaches, line-edge roughness however remains an important issue. The team believes that this LER can be further reduced, e.g. by choosing the correct resist material and improving on resist smoothening. 

Top-down SEM images for the three patterning flows to enable 16nm pitch gratings: (top) EUV-based SADP, (middle) EUV-based SAQP and (bottom) 193nm immersion-based SAOP. Line-edge roughness values for all three options are shown for the final patterns of 8nm lines and trenches [as presented at 2019 SPIE Advanced Lithography].

Top-down SEM images for the three patterning flows to enable 16nm pitch gratings: (top) EUV-based SADP, (middle) EUV-based SAQP and (bottom) 193nm immersion-based SAOP. Line-edge roughness values for all three options are shown for the final patterns of 8nm lines and trenches [as presented at 2019 SPIE Advanced Lithography].

eSALELE: a different approach to integrate blocks

All three multi-patterning approaches have one thing in common: first, the lines and trenches are printed, and later on, blocks are added – using e.g. a self-aligned block approach. The imec team also investigated a different approach using EUVL – called eSALELE – where lines and blocks are defined throughout the same process flow. Besides a relatively high LER, an additional drawback of this approach is the use of four EUV masks (two for the lines and two for the blocks) – making this concept more costly. Stefan Decoster: “But the main advantage of the eSALELE approach is the flexibility in design, and the avoidance of ‘dummy’ metal lines – printed lines that are not really needed for the chips operation. Avoiding these lines is beneficial for the RC delay and power consumption in the back-end-of-line.” The team is currently exploring the feasibility of printing 16nm pitch lines with the eSALELE technique. 

Single exposure EUVL entering the memory field: the case of STT-MRAM

Due to its high writing and reading speed, STT-MRAM has recently emerged as a promising candidate for replacing SRAM-based last-level cache memories. The core element of an STT-MRAM device is a pillar-like magnetic tunnel junction, in which an insulating layer is sandwiched between two thin ferromagnetic layers which are the fixed and the free layers. The magnetic tunnel junction can exist in two different resistance states: a low resistance state (LRS, with the magnetization of the two magnetic layers in parallel) and a high resistance state (HRS, with the magnetization in an antiparallel state). Writing of the memory cell is performed by switching the magnetization for the free magnetic layer, by means of a current that is injected into the magnetic tunnel junction. The read operation relies on tunnel magnetoresistance (TMR), which is a function of the resistance difference between the two resistance states.

From immersion lithography to single exposure EUVL

So far, the pillars – i.e. the stacked layers forming the magnetic tunnel junction – have been patterned with 193nm immersion lithography to achieve 200nm, and, later on, 100nm pitch pillar pitches. Murat Pak, R&D engineer at imec: “But in order to meet the high-density requirement for future memories, we need tighter pitches such as 50nm or less – with pillar diameters of around 20nm (i.e., the pillar CD after full patterning). These aggressive pitches can no longer be achieved with immersion lithography, and this highlights the need for introducing single exposure EUVL.”

Introducing LCDU as the most critical metric

At these small dimensions, the impact of roughness and stochastic failures can however no longer be neglected – calling for improved patterning techniques. “For this memory application, the most critical parameter turns out to be the local CD uniformity (or LCDU), which is a measure for the pillar roughness,” explains Murat Pak. “This LCDU will obviously impact the resistance variation, and hence the read performance of the STT-MRAM cell. Therefore, ensuring a good LCDU is critical in STT-MRAM manufacturing.” 

(Left) Demonstration of the resistance states and the allowed variations; (right) X-SEM image of the pillars

(Left) Demonstration of the resistance states and the allowed variations; (right) X-SEM image of the pillars (as presented at 2019 SPIE Advanced Lithography).

 In order to optimize the LCDU of the magnetic tunnel junction pillars, different EUV litho processes have been proposed and compared. Murat Pak: “First, we considered different resists, including the well-known chemically amplified resist (or CAR, which was initially optimized for 193nm immersion lithography), and two different MCR (or metal containing) resists. Second, our team screened different underlayers (including spin-on carbon and spin-on glass) – which is the layer underneath the resist – and studied their impact on the performance of the resist material. And finally, we studied different tonalities, in particular a negative tone CAR resist (creating pillars) and a positive tone resist in combination with a tone reversal process (‘turning’ holes into pillars).” The team also checked if the targeted improvements on the LCDU were transferred to the etch process. For all experiments, exposures have been performed using an ASML TWINSCAN NXE:3300B.

Illustration of the tone reversal process: (left) holes obtained with a positive tone CAR resist and (right) pillars obtained after tone reversal (as presented at 2019 SPIE Advanced Lithography).

Illustration of the tone reversal process: (left) holes obtained with a positive tone CAR resist and (right) pillars obtained after tone reversal (as presented at 2019 SPIE Advanced Lithography).

Three promising approaches

As a main conclusion, the two most promising approaches in terms of LCDU have been obtained with one type of MCR resist. A third option – making use of the tone reversal process – also performed well, mainly in terms of pillar LCDU as well. “For all three approaches, we obtained an improvement above 20% for the LCDU performance,” adds Murat Pak. “This is an important step towards the targeted LCDU of 1.55nm after full patterning.” For these promising litho process options, other performance metrics such as process window analysis, pillar circularity and critical dimension uniformity (i.e. CD uniformity within one or different wafers) have been verified as well.

In summary

In this article, various EUVL patterning approaches have been proposed for future logic and memory (i.e., SST-MRAM) applications. For logic, the performance of EUV-based SADP, EUV-based SAQP and EUV-based SALELE were compared with immersion-based SAOP. All options have the potential of printing metal line pitches and trenches as aggressive as 16nm. However, trade-offs have to be made in terms of process complexity, cost-of-ownership, freedom in design, and line-edge roughness. For SST-MRAM, three different EUV-based approaches have been identified for printing 50nm pitch magnetic tunnel junction pillars, with promising LCDU performance. 

Want to know more?

  • This work has been presented in two papers at the 2019 SPIE Advanced Lithography Conference – which can be requested via this link:
    • ‘Exploration of EUV-based self-aligned multipatterning options targeting pitches below 20nm’, S. Decoster et al.
    • ‘LCDU optimization of STT-MRAM 50nm pitch MTJ pillars for process window improvement’, M. Pak et al. 
       
  • This imec magazine article summarizes earlier progress towards enabling EUVL single exposure of 32nm pitch metal2 layers and of 36nm contact holes, and towards understanding the stochastic failure mechanisms (presented at 2018 SPIE Advanced Lithography). 
     
  • Imec recently presented the 2019 Lifetime of Innovation Award to ASML CTO Martin van den Brink. Read the press release
     
  • Take a look at our recent press releases related to EUV lithography:
    • Imec to install high-NA EUV imaging and attosecond analytical lab to probe lithography down to 8nm pitch, press release
    • Sequential Infiltration Synthesis (SIS) significantly improves EUV patterning, press release
    • Imec and ASML enter next stage of EUV lithography collaboration, press release

 

Imec honors ASML President and CTO Martin van den Brink with Lifetime of Innovation Award

With the Imec Lifetime of Innovation Award, imec acknowledges the personal contribution of Martin van den Brink – known as the ‘father’ of ASML – to the success story of the company, which has grown into the absolute world leader in the development of lithography equipment for the chip industry. And this success of ASML is an essential chapter of the success story of the semiconductor industry.

Martin receiving this year’s Imec Lifetime of Innovation Award is no coincidence, as both imec and ASML celebrate their 35thanniversary. On top of that, 2019 is the year that the first chips with EUV-printed structures will go into high-volume production. ASML has worked for more than 20 years on the development of this advanced lithography technology. With this award, which is each year presented to people having transformed the semiconductor industry, imec recognizes Martin van den Brink’s tireless efforts in realizing EUV lithography – from idea to reality. This powerful lithography technique is key to advancing the chip industry. It is key to enable Moore’s law scaling, cost reduction and increased performance of advanced microchips.

Martin van den Brink, President and CTO of ASML, received the award from Luc Van den hove, President and CEO of imec, during the Imec Technology Forum Belgium – one of the three conferences that were part of imec’s 2019 FutureSummits. Earlier recipients of the award include Dr. Morris Chang (TSMC), Dr. Gordon Moore (Intel), Dr. Kinam Kim (Samsung) and Dr. Irwin Jacobs (Qualcomm).

About Stefan Decoster

Stefan Decoster holds an M.Sc. degree in physics from KU Leuven, where he also received a PhD degree in physics in 2009 on ion implantation-related lattice damage in semiconductors. After working one year as a post-doctoral researcher at the National University of Australia in Canberra, he joined imec in 2012 as an R&D dry etch engineer. He is specialized in back-end-of-line (BEOL) dry etch processing, with a strong focus on dimensional scaling through multi-patterning schemes and self-aligned patterning approaches.

About Murat PAK

Murat PAK was born in Turkey, in 1986. He received the B.S. degree in electronics engineering from the Istanbul Technical University, Turkey, in 2008. In 2011, he has received the M.Sc. degree in electrical and electronics engineering from the Bogazici University. The master thesis has been completed in the Department of Electrical Engineering (ESAT) of KU Leuven, Belgium. In 2010, he has joined the Semiconductor Technologies Research Lab of the National Scientific Council of Turkey, Tubitak, as a research engineer and worked there as a senior research engineer until early 2017, when he joined imec as an R&D engineer. Both in Tubitak and imec, he has focused on the process development of the lithography steps of semiconductor manufacturing. At imec, he mainly focuses on the litho development of the memory projects.

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